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Technical Paper

Analysis of Degradation Mechanism of Lead-Free Materials

2009-04-20
2009-01-0260
The use of lead-free (Pb-free) solder and plating in onboard electronic components has accelerated rapidly in recent years, but solutions have yet to be found for the issues of whisker generation in tin (Sn) plating and crack initiation in Pb-free solder, despite widespread research efforts. Analysis of the whisker generation mechanism has focused on internal energy levels and crystal orientation, and analysis of the crack initiation mechanism in Pb-free solder has examined changes in the grain boundaries of Sn crystals.
Journal Article

Development of Bio-Based Plastics for Injection Molding

2009-04-20
2009-01-0019
Technological development of materials derived from plants (e.g., polylactic acid (PLA), and the like) is required to break dependence on fossil fuels and reduce CO2. PLA has inferior hydrolysis resistance, impact resistance, and molding ability than polypropylene (PP), and in order to overcome these disadvantages, a novel PP/PLA alloy has been conceived where PLA is incorporated into a PP matrix. By optimizing compatibilizer and elastomer addition, PLA has been successfully dispersed into a PP matrix at a sub-micron order, and interior parts have been successfully developed that fulfill the performance, appearance, and mass-production capability requirements for practical application.
Journal Article

Development of Hardening Depth Evaluation Technique using Eddy Current – Establishment and Introduction of In-line Hardening Depth Inspection System –

2009-04-20
2009-01-0867
A hardening depth evaluation technique using eddy current has been developed, which can be applied to a mass production line for destructive (cutting) inspections. Using this technique, changes in the hardness of the induction-hardened structure can be detected based on the changes in magnetic permeability. This technique reduces the thermal effect and improves measurement accuracy through a multi-frequency exciting method and a difference method algorithm.
Journal Article

Narrow-Band Omnidirectional Structural Color

2008-04-14
2008-01-1049
Automotive pigments consist of absorptive materials which absorb most of the wavelengths of light in the visible range (400-800 nm) except one particular range which gets reflected and seen as color. This coloring mechanism based on light absorption due to their molecular structure generally reflects a broader range of wavelength with a moderate reflectivity (50-60%). However in nature we find many magnificent colors in insects, butterflies, birds and fishes. These colors in nature are not based on the abortive pigments, but on the nanoscopic regular structures that interfere light reflected from those periodic sites. Since animals contain no solid metals, to produce metallic-like reflections they also rely on interference of light.[1] Most common and well-known form of animal reflector is the multilayer type where alternating high and low refractive index layers are formed. Such nanostructure assembly can reflect light up to 100%.
Journal Article

Study of Alternative Oxygen Reduction Electrocatalyst for Pt Based on Transition Metal Chalcogenides

2008-04-14
2008-01-1265
The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.
Journal Article

Measurement of Oil Film Pressure in the Main Bearings of an Operating Engine Using Thin-Film Sensors

2008-04-14
2008-01-0438
We developed a technique to measure oil film pressure distribution in engine main bearings using thin-film pressure sensors. The sensor is 7μm in thickness, and is processed on the surface of an aluminum alloy bearing. In order to increase the durability of the sensor, a layer of MoS2 and polyamide-imide was coated on thin-film sensors. This technique was applied to a 1.4L common-rail diesel engine operated at a maximum speed of 4,500r/min with a 100Nm full load, and the oil film pressure was monitored while the engine was operating. The measured pressure was compared with calculations based on hydrodynamic lubrication (HL) theory.
Technical Paper

Development of Reduction Method for Whirl Noise on Turbocharger

2007-10-29
2007-01-4018
The whirl noise on turbochargers is generated by the self-induced vibration of the oil film in the bearing system. The noise is characterized by its frequency behavior that doesn't increase proportionately to the turbo shaft speed. It tends to be felt annoying. In this paper, to improve the whirl vibration, a statistical analysis approach was applied to the bearing specifications. The results from experiments showed that the bearing clearances played an important role in the reduction of the whirl vibration. To further investigate into this phenomenon, the shaft oscillation behavior was measured. And a vibration simulation program for the turbocharger bearing system was also developed.
Technical Paper

Experimental Analysis of Acoustic Coupling Vibration of Wheel and Suspension Vibration on Tire Cavity Resonance

2007-05-15
2007-01-2345
It is difficult to improve tire cavity noise since the pressure of cavity resonance acts as a compelling force, and its low damping and high gain characteristics dominate the vibration of both the suspension and body. For this reason, the analysis described in this article aimed to clarify the design factors involved and to improve this phenomenon at the source. This was accomplished by investigating the acoustic coupling vibration mode of the wheel, which is the component that transmits the pressure of cavity resonance at first. In addition, the vibration characteristic of suspension was investigated also. A speaker-equipped sound pressure generator inside the tire and wheel assembly was developed and used to infer that wheel vibration under cavity resonance is a forced vibration mode with respect to the cavity resonance pressure distribution, not an eigenvalue mode, and this phenomenon may therefore be improved by optimizing the out-of-plane torsional stiffness of the disk.
Technical Paper

Development of Sealing Material Used in the Body Welding Shop

2007-04-16
2007-01-0418
1 The principal characteristics required of sealing materials used in the body shop have focused on their adhesion to oily steel sheets and quick curing performance. Means for attaining these characteristics have been narrowed down to a basic resin system and a curing system. Various techniques have been studied to ensure proper anti-corrosion performance at the sealer application boundaries and thin application areas. They include the addition of anti-corrosion fillers, the provision of conductivity (through electro-deposition), and the application of a micro foam film over the application boundaries. Thus, prospects for attaining the same level of anti-corrosion performance as existing materials have been achieved.
Technical Paper

Development of Suspension Design Technology Applying Principal Elastic Axes

2007-04-16
2007-01-0857
Automobile manufacturers have increased the pace of vehicle development in recent years to respond to diverse market demands. Consequently, it has become crucial for manufacturers to develop new technology which enables a particular vehicle to simultaneously achieve both ride comfort and handling performance at an optimal level. This article introduces the suspension design technology applying the Principal Elastic Axes that has been developed by our company for use in its vehicles. These axes, which consist of three translational and three rotational axes, represent the set of fully decoupled stiffness axes. Applying the Principal Elastic Axes to the suspension reduces the number of design parameters, which enables suspension movements to be considered totally and simply.
Technical Paper

Achievements and Exploitation of the AUTOSAR Development Partnership

2006-10-16
2006-21-0019
Reductions of hardware costs as well as implementations of new innovative functions are the main drivers of today's automotive electronics. Indeed more and more resources are spent on adapting existing solutions to different environments. At the same time, due to the increasing number of networked components, a level of complexity has been reached which is difficult to handle using traditional development processes. The automotive industry addresses this problem through a paradigm shift from a hardware-, component-driven to a requirement- and function-driven development process, and a stringent standardization of infrastructure elements. One central standardization initiative is the AUTomotive Open System ARchitecture (AUTOSAR). AUTOSAR was founded in 2003 by major OEMs and Tier1 suppliers and now includes a large number of automotive, electronics, semiconductor, hard- and software companies.
Technical Paper

Development of a Method to Predict the Rupture of Spot Welds in Vehicle Crash Analysis

2006-04-03
2006-01-0533
This paper describes a new method to predict the rupture of spot welds, suitable for vehicle crash simulation. In a crash simulation used for vehicle development process, the calculation is performed assuming that the spot welds in the vehicle do not rupture. However, if some spot welds rupture in test of a prototype vehicle, the simulated deformation and test deformation may not match, resulting in inaccurate estimation of deformation from simulation. Therefore accuracy of predicting the rupture of spot welds is crucial in accurately estimating the deformation and improving reliability of vehicle crash simulation results. The new method to predict the rupture of spot welds which relates axial and shear forces and bending moment of spot weld to stress around nugget has been developed by authors. Based on developed method, the rupture risk of spot welds has been estimated. The new method was applied to estimate the spot weld rupture using three types of specimens.
Technical Paper

Study of Plastic Plating Using Highly Concentrated Ozonized Water Pretreatment

2005-04-11
2005-01-0618
In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).
Technical Paper

Application of Structural Color Technology for Automotive Paint

2005-04-11
2005-01-0617
Currently, to achieve the desired design in automotive paint, absorption pigments, such as organic pigments, are used in combination with brilliant pigments (ex. aluminum or mica etc.). However, many beautiful colors exist in the world, especially in the natural world. Until now, automotive paints have not been able to replicate those colors. In this project, by first analyzing the coloring principles of the natural world, we have focused on the development of a previously non-existent coloring technology (structural color). By combining this with nanostructure control technology, we have established a radically new coloring process enabling the design of hues, chromaticity and reflection intensity. This technology has tangible results, as new pigments are available for paint formulations.
Technical Paper

Research in Aluminum Matrix Composites for Improvement in Damping Capacity

2005-04-11
2005-01-1389
We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.
Technical Paper

Electronically-Scanning Millimeter-Wave RADAR for Forward Objects Detection

2004-03-08
2004-01-1122
Recently, the development of advanced automotive technology for excellent safety and convenience has become more active. Efforts have focused on the development of active safety technology. Pre-Crash Systems, such as passenger protection systems activated before a collision or collision speed reduction system, which are categorized between active safety systems and passive safety systems, have been a subject of focus. In such systems, surround sensing technology to predict a collision is the key issue. We developed an electronically scanning millimeter-wave (MMW) RADAR, which uses Digital Beam Forming (DBF) technology, as one of the first in the world for automotive applications.
Technical Paper

Analysis and Simplification of Thermal Endurance Tests of NOx Storage-Reduction Catalysts

2004-03-08
2004-01-1496
Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).
Technical Paper

Analysis of Potassium Storage Components in NOx Catalysts Application of Analytical Techniques and DFT Computations to Catalytic Analysis

2004-03-08
2004-01-1494
By using analytical techniques (FT-IR, TG-MS, ICP) and DFT calculations, the potassium (K) used as a storage component in NOx Catalysts can be analyzed. The results from this study show that the, K exists as K2CO3, and that the amount, molecular structure, and thermal stability of K2CO3 are different, depending on the support material (ZrO2, Al2O3, or TiO2). If the amount of K that interacts with the support to form an inactive complex oxide is decreased, the amount of K2CO3 and NOx storage is increased. The amount of the inactive K varies with the basicity of the supports. K2CO3 that exists in unstable structures on the supports can be easy to react with NOx to form the nitrate. So, the higher the quantity of unstable K2CO3, the higher the NOx storage capacity. Based on these results, a development guideline was proposed to improve the NOx storage performance.
Technical Paper

Metallic Powder Coating for Aluminum Wheels

2004-03-08
2004-01-1671
From the viewpoint of measures for environmental issues, the amount of solvents in paint for aluminum wheels needs to be minimized. Environmentally friendly powder coatings have been used widely for primer coating and clear coating, but there is no precedent for its use for base coating. This time, we optimized the condition of surface treatment of pigment and hardening behavior of constituent resin in the melting process and succeeded in developing a metallic powder coating for aluminum wheels that fulfills the appearance and the quality requirements of aluminum wheels.
Technical Paper

Introduction of Durable Surface Conditioner Before E-Coat

2004-03-08
2004-01-1672
Toyota Motor Corporation has been developing technologies for reductions on the environmental load. This paper reports the following as a part of technological development for the painting process. Prior to the application of the E-coat, vehicle bodies are pretreated with zinc phosphates. This is applied to ensure good adhesion and corrosion resistance of the E-coat film. To obtain an excellent pretreatment film, surface conditioning with titanium colloid is generally applied before pretreatment. Since colloid flocculation control was difficult in the case of a conventional titanium colloid-type surface conditioner, the surface conditioner had to be renewed at approximately two-month intervals. The liquid life, however, increased remarkably as a result of adopting fine zinc-type surface conditioners and adding an organic protective surface layer. The water supply/discharge amount was decreased significantly compared with previous amounts.
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